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i'm about 3 weeks into veg and this guy has developed brownish spots along the leaves. the leaves are also brittle and curl upward? is this a Mg problem? should i use epsom salt? the other ones leaves just started to droop the other day?? not sure, maybe over water? what about being rootbound?

I just germinated a couple seeds and one of them has the root looking healthy but it's taken like a 180 and kinda curled back towards the fat end of the seed.. how would i plant this?? will the root automatically grow down if i still put it in pointy side down even if the tip of the root would...