I did this, it was tricky though! You can but what you must remember is that you now pressurize the chimney by adding your ventilation. What happened to me was my water heater gas was coming back out of the top, you can check the opening with a lighter to see if air is being sucked in or blowing out, (its supposed to be sucking in) I dont know what your connection looks like, but if the connection just opens to the chimney flue it will pressurize the chimney too much and force air out all the easy places first which is probably not the top of the chimney. I had to stick a 90degree swivel elbow and run it into the chimney so the air is aimed up the chimney giving it direction and sending flying up the chimney instead of just dumping out and pressurizing the chimney to be forced out the top. Always check for back flow from your furnace or water heater, you may have to get a back flow prevention flange because YOU COULD DIE, a CO monitor would help save your tushie though, hope this helps.