1) With the window, i suggest you put some net curtains up, then regular curtains over that but pin it tightly around the window. You want to make it look as perfectly normal as possible from the outside. Seeing a blocked off window could look suspect. You can get some seriously thick curtains from shops that sell home stuff, just explain to the sales person you work nights and you get disturbed by daylight coming into the room and ask her to recommend something suitable.
2) Depending on your bank roll, on a rool that size, you are looking at large costs for mylar, and even larger costs for C3 AD film. I would think that you could use the money better on a couple more lights to get coverage, or get better reflectors. Mylar is normally only used for boxes and closets, but an entire room, ouch. If you DO go down this route, i suggest you spend some money on some good sunglasses too
If it is a matter of anti detection (since you mentioned C3 AD film) this would be an extreme cost and depending on your grow size, you may want to think of the scale/cost/risk factor. C3 AD film, from what i can see, is for massive farms on a professional scale. If detection is a large risk, you may want to re-think the location. If it is just for light reflection, most grow rooms are just matt white. Certainly a cost effective option.
3) If its too hot for your walls, your plants are already dead lol. Keep your room at a consistent 23-25 degrees Celsius and humidity at about 40-60%. This is no different than having the heating on full in your house, so the walls will be fine. I would scrap the wall paper though, as that will probably peel from the humidity.
4) Ventilation would need to circulate the total volume of the room every few minutes (5 minutes max). So assuming you have a ceiling height of 8', you need a fan/filter kit that can deal with at least 120 square feet per minute, although i would suggest massively over sizing this and get at least 300 sqr ft/min. Last thing you want is to have to change your set up because your grow is more stinky than expected. Get the best filters you can afford. You will also want oscillating fans to keep the air flowing, and also to blow your plants around a bit (simulated wind makes them grow stronger). Best to set your room up, set your temp gauges up around the room (2 digital ones should be enough, one each end of the room) and do a dry run of the temps. Ignore the humidity as this will drastically increase with plants in the room. Try different things like with/without the fans, and see how it makes a difference. Leave running for an hour or more to let it heat up enough.
Ozone generators are also a good idea, fairly cheap for what they are.
Another thing you may want to take into consideration is splitting your room in two. 1/3 veg room, 2/3 flowering and curing (not half and half because flowering plants can double in size) unless you are expecting one crop every 3 months and not a cycle. If you cycle (having different plants vegging and flowering at the same time) then you want to create 2 rooms out of the one. The light from one should not spread into the other. This, of course, creates 2 more wall faces for you to paint/mylar, so extra cost.
Hope this helps. Good luck.