I use a little bit of rockwool soak treatment, but for the most part, I have found that to get the PH to stop rising on Rockwool, make sure that you soak it thoroughly before use.
I don't mean throw it in a tub for 24 hours like everyone suggests. That is good, but the KEY is to RUN water through it for at least an hour. Just flush the shit out of your cubes in a bathtub faucet for at least an hour. My PH BARELY rises anymore now that I do that. I adjust my ph maybe once a week depending on how much water I have top up with in my resevoir. Used to see it climb daily, now it doesn't climb hardly at all.